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Catalytic reduction of N(2) to NH(3) by an Fe-N(2) complex featuring a C-atom anchor
While recent spectroscopic studies have established the presence of an interstitial carbon atom at the center of the iron-molybdenum cofactor (FeMoco) of MoFe-nitrogenase, its role is unknown. We have pursued Fe-N(2) model chemistry to explore a hypothesis whereby this C-atom (previously denoted as...
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| Glavni autori: | , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2014
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3933546/ https://ncbi.nlm.nih.gov/pubmed/24350667 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja4114962 |
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