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Tripodal P(3)(X)Fe–N(2) Complexes (X = B, Al, Ga): Effect of the Apical Atom on Bonding, Electronic Structure, and Catalytic N(2)-to-NH(3) Conversion
Terminal dinitrogen complexes of iron ligated by tripodal, tetradentate P(3)(X) ligands (X = B, C, Si) have previously been shown to mediate catalytic N(2)-to-NH(3) conversion (N(2)RR) with external proton and electron sources. From this set of compounds, the tris(phosphino)borane (P(3)(B)) system i...
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| Udgivet i: | Inorg Chem |
|---|---|
| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2021
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8279418/ https://ncbi.nlm.nih.gov/pubmed/33410667 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.0c03354 |
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