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Characterization of an Fe≡N-NH(2) Intermediate Relevant to Catalytic N(2) Reduction to NH(3)
The ability of certain transition metals to mediate the reduction of N(2) to NH(3) has attracted broad interest in the biological and inorganic chemistry communities. Early transition metals such as Mo and W readily bind N(2) and mediate its protonation at one or more N atoms to furnish M(N(x)H(y))...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4603982/ https://ncbi.nlm.nih.gov/pubmed/26000443 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b03432 |
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