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N–H Bond Dissociation Enthalpies and Facile H Atom Transfers for Early Intermediates of Fe–N(2) and Fe–CN Reductions
Fe-mediated biological nitrogen fixation is thought to proceed via either a sequence of proton and electron transfer steps, concerted H atom transfer steps, or some combination thereof. Regardless of the specifics and whether the intimate mechanism for N(2)-to-NH(3) conversion involves a distal path...
Shranjeno v:
| izdano v: | J Am Chem Soc |
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| Main Authors: | , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2017
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5517100/ https://ncbi.nlm.nih.gov/pubmed/28140600 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b12861 |
| Oznake: |
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