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Fe–N(2)/CO complexes that model a possible role for the interstitial C atom of FeMo-cofactor (FeMoco)
We report here a series of four- and five-coordinate Fe model complexes that feature an axial tri(silyl)methyl ligand positioned trans to a substrate-binding site. This arrangement is used to crudely model a single-belt Fe site of the FeMo-cofactor that might bind N(2) at a position trans to the int...
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| Principais autores: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3791750/ https://ncbi.nlm.nih.gov/pubmed/24043796 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1310153110 |
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