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H–H and Si–H Bond Addition to Fe(≡)NNR(2) Intermediates Derived from N(2)
The synthesis and characterization of Fe diphosphineborane complexes are described in the context of N(2) functionalization chemistry. Iron aminoimides can be generated at RT under 1 atm N(2) and are shown to react with E–H bonds from PhSiH(3) and H(2). The resulting products derive from delivery of...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3770781/ https://ncbi.nlm.nih.gov/pubmed/23472709 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja400836u |
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