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Transformation of an [Fe(η(2)-N(2)H(3))](1+) Species to π-Delocalized [Fe(2)(μ-N(2)H(2))](2+/1+) Complexes

[Image: see text] A monomeric iron Fe(η(2)-N(2)H(3)) species has been prepared, and exposure to oxygen yields a diiron complex that features five-coordinate iron centers and an activated bridging diazene ligand (NH=NH). Combined structural, theoretical, and spectroscopic data for the redox pair of c...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Prif Awduron: Saouma, Caroline T., Kinney, R. Adam, Hoffman, Brian M., Peters, Jonas C.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2011
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC3236637/
https://ncbi.nlm.nih.gov/pubmed/21394860
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201006299
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