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Transformation of an [Fe(η(2)-N(2)H(3))](1+) Species to π-Delocalized [Fe(2)(μ-N(2)H(2))](2+/1+) Complexes
[Image: see text] A monomeric iron Fe(η(2)-N(2)H(3)) species has been prepared, and exposure to oxygen yields a diiron complex that features five-coordinate iron centers and an activated bridging diazene ligand (NH=NH). Combined structural, theoretical, and spectroscopic data for the redox pair of c...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3236637/ https://ncbi.nlm.nih.gov/pubmed/21394860 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201006299 |
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