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Modeling the Signatures of Hydrides in Metalloenzymes: ENDOR analysis of a di-iron Fe(μ-NH)(μ-H)Fe core
The application of 35 GHz pulsed EPR and ENDOR spectroscopies has established that the biomimetic model complex L(3)Fe(μ-NH)(μ-H)FeL(3) (L(3) = [PhB(CH(2)PPh(2))(3)](-)) complex, 3, is a novel S = ½ type-III mixed-valence di-iron II/III species, in which the unpaired electron is shared equally betwe...
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| Huvudupphovsmän: | , , , |
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| Materialtyp: | Artigo |
| Språk: | Inglês |
| Publicerad: |
2012
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| Ämnen: | |
| Länkar: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3433054/ https://ncbi.nlm.nih.gov/pubmed/22823933 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja303739g |
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