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Fe(I)-mediated reductive cleavage and coupling of CO(2): An Fe(II)(μ-O,μ -CO)Fe(II) core
THF solutions of a new iron(I) source, “[PhBP(CH2Cy)(3)]Fe” ([PhBP(CH2Cy)(3)] = [PhBP(CH(2)P(CH(2)Cy)(2))(3)](−)), effect the reductive cleavage of CO(2) via O-atom transfer at ambient temperature. The dominant reaction pathway is bimetallic and leads to the formation of a structurally unprecedented...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2888261/ https://ncbi.nlm.nih.gov/pubmed/17199260 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja065524z |
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