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A 10(6)-Fold Enhancement in N(2)-Binding Affinity of an Fe(2)(μ-H)(2) Core upon Reduction to a Mixed-Valence Fe(II)Fe(I) State
[Image: see text] Transient hydride ligands bridging two or more iron centers purportedly accumulate on the iron–molybdenum cofactor (FeMoco) of nitrogenase, and their role in the reduction of N(2) to NH(3) is unknown. One role of these ligands may be to facilitate N(2) coordination at an iron site...
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| Glavni autori: | , , |
|---|---|
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
American Chemical
Society
2014
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| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4183624/ https://ncbi.nlm.nih.gov/pubmed/25184795 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja507217v |
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