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Mononuclear Fe(I) and Fe(II) Acetylene Adducts and Their Reductive Protonation to Terminal Fe(IV) and Fe(V) Carbynes

The activity of nitrogenase enzymes, which catalyze the conversion of atmospheric dinitrogen to bioavailable ammonia, is most commonly assayed by the reduction of acetylene gas to ethylene. Despite the practical importance of acetylene as a substrate, little is known concerning its binding or activa...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Citek, Cooper, Oyala, Paul H., Peters, Jonas C.
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6800224/
https://ncbi.nlm.nih.gov/pubmed/31430146
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b06987
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