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Nitrogen Fixation via a Terminal Fe(IV) Nitride
Terminal iron nitrides (Fe≡N) have been proposed as intermediates of (bio)catalytic nitrogen fixation, yet experimental evidence to support this hypothesis has been lacking. In particular, no prior synthetic examples of terminal Fe≡N species have been derived from N(2). Here we show that a nitrogen-...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6021180/ https://ncbi.nlm.nih.gov/pubmed/28992418 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b09364 |
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