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Characterization of the earliest intermediate of Fe-N(2) protonation: CW and Pulse EPR detection of an Fe-NNH species and its evolution to Fe-NNH(2)(+)
Iron diazenido species (Fe(NNH)) have been proposed as the earliest intermediates of catalytic N(2)-to-NH(3) conversion (N(2)RR) mediated by synthetic iron complexes, and relatedly as intermediates of N(2)RR by nitrogenase enzymes. However, direct identification of such iron species, either during o...
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| Pubblicato in: | J Am Chem Soc |
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| Autori principali: | , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2019
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6636918/ https://ncbi.nlm.nih.gov/pubmed/31046258 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b12082 |
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