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Synthetic Models for the [FeFe]-Hydrogenase: Catalytic Proton Reduction and the Structure of the Doubly Protonated Intermediate

This report compares biomimetic HER catalysts with and without the amine cofactor (adt(NH)): Fe(2)(adt(NH))(CO)(2)(dppv)(2) (1(NH)) and Fe(2)(pdt)(CO)(2)(dppv)(2) (2; (adt(NH))(2−) = (HN(CH(2)S)(2)(2−), pdt(2−) = 1,3-(CH(2))(3)S(2)(2−)). These compounds are spectroscopically, structurally, and stere...

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Bibliografiska uppgifter
Huvudupphovsmän:	Carroll, Maria E., Barton, Bryan E., Rauchfuss, Thomas B., Carroll, Patrick J.
Materialtyp:	Artigo
Språk:	Inglês
Publicerad:	2012
Ämnen:	Article
Länkar:	https://ncbi.nlm.nih.gov/pmc/articles/PMC3514462/ https://ncbi.nlm.nih.gov/pubmed/23126330 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja309216v
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Synthetic Models for the [FeFe]-Hydrogenase: Catalytic Proton Reduction and the Structure of the Doubly Protonated Intermediate

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