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Aza- and Oxadithiolates Are Proton Relays in Functional Models for the [FeFe]-Hydrogenases
[Image: see text] The dithiolate cofactor for the [FeFe]-hydrogenase models, Fe(2)(xdt)(CO)(2)(dppv)(2) (where xdt = 1,3-propanedithiolate (pdt), azadithiolate (adt), (SCH(2))(2)NH, and oxadithiolate (odt), (SCH(2))(2)O; dppv = cis-1,2-bis-(diphenylphosphino)ethylene) have been probed for their func...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2646893/ https://ncbi.nlm.nih.gov/pubmed/19053433 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja8057666 |
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