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Aza- and Oxadithiolates Are Proton Relays in Functional Models for the [FeFe]-Hydrogenases

[Image: see text] The dithiolate cofactor for the [FeFe]-hydrogenase models, Fe(2)(xdt)(CO)(2)(dppv)(2) (where xdt = 1,3-propanedithiolate (pdt), azadithiolate (adt), (SCH(2))(2)NH, and oxadithiolate (odt), (SCH(2))(2)O; dppv = cis-1,2-bis-(diphenylphosphino)ethylene) have been probed for their func...

詳細記述

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書誌詳細
主要な著者: Barton, Bryan E., Olsen, Matthew T., Rauchfuss, Thomas B.
フォーマット: Artigo
言語:Inglês
出版事項: 2008
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC2646893/
https://ncbi.nlm.nih.gov/pubmed/19053433
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja8057666
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