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Diiron bridged-thiolate complexes that bind N(2) at the Fe(II)Fe(II), Fe(II)Fe(I), and Fe(I)Fe(I) redox states
All known nitrogenase cofactors are rich in both sulfur and iron and are presumed capable of binding and reducing N(2). Nonetheless, synthetic examples of transition metal model complexes that bind N(2) and also feature sulfur donor ligands remain scarce. We report herein an unusual series of low va...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4603983/ https://ncbi.nlm.nih.gov/pubmed/26039253 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b04738 |
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