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Alkali Metal Variation and Twisting of the FeNNFe Core in Bridging Diiron Dinitrogen Complexes
[Image: see text] Alkali metal cations can interact with Fe–N(2) complexes, potentially enhancing back-bonding or influencing the geometry of the iron atom. These influences are relevant to large-scale N(2) reduction by iron, such as in the FeMoco of nitrogenase and the alkali-promoted Haber–Bosch p...
Tallennettuna:
| Julkaisussa: | Inorg Chem |
|---|---|
| Päätekijät: | , , , , , |
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
American
Chemical Society
2016
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| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4856002/ https://ncbi.nlm.nih.gov/pubmed/26925968 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.5b02841 |
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