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Cobalt-Dinitrogen Complexes With Weakened N-N Bonds

[Image: see text] Reported N(2) complexes of cobalt do not have substantial weakening of the N-N bond. Using diketiminate ligands to enforce three-coordinate geometries, we have synthesized several novel CoNNCo complexes. In formally univalent complexes, cobalt is poorer than iron at weakening the N...

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Detalhes bibliográficos
Main Authors: Ding, Keying, Pierpont, Aaron W., Brennessel, William W., Lukat-Rodgers, Gudrun, Rodgers, Kenton R., Cundari, Thomas R., Bill, Eckhard, Holland, Patrick L.
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2746749/
https://ncbi.nlm.nih.gov/pubmed/19537787
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja808783u
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