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Cobalt-Magnesium and Iron-Magnesium Complexes with Weakened Dinitrogen Bridges
The cooperative binding of N(2) by late transition metals and main-group metals is a promising strategy for N-N bond weakening and activation. We report the use of activated Rieke magnesium for reduction of iron and cobalt complexes supported by bulky β-diketiminate ligands. Binding of N(2) is accom...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3869404/ https://ncbi.nlm.nih.gov/pubmed/24367236 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejic.201300187 |
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