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The Mechanism of N-N Double Bond Cleavage by an Iron(II)-Hydride Complex
The use of hydride species for substrate reductions avoids strong reductants, and may enable nitrogenase to reduce multiple bonds without unreasonably low redox potentials. In this work, we explore the N=N bond cleaving ability of a high-spin iron(II) hydride dimer with concomitant release of H(2)....
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| Publicado en: | J Am Chem Soc |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2016
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5499983/ https://ncbi.nlm.nih.gov/pubmed/27598037 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b04654 |
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