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Borane B-C Bond Cleavage by a Low-Coordinate Iron Hydride Complex and N-N Bond Cleavage by the Hydridoborate Product
The iron(II) hydride dimers [L(R)Fe(μ-H)(2)FeL(R)] (L(Me) = 2,4-bis(2,6-diisopropylphenylimino) pent-3-yl; L(tBu) = 2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimino)hept-4-yl) abstract hydrocarbyl groups from BR′(3) (R′ = Et, Ph) to give L(R)FeR′ and L(R)Fe(μ-H)(2)BR′(2). Mechanistic studies w...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2518744/ https://ncbi.nlm.nih.gov/pubmed/18725998 |
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