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Synthesis, Characterization, and Nitrogenase-Relevant Reactions of an Iron Sulfide Complex with a Bridging Hydride
[Image: see text] The FeMoco of nitrogenase is an iron–sulfur cluster with exceptional bond-reducing abilities. ENDOR studies have suggested that E(4), the state that binds and reduces N(2), contains bridging hydrides as part of the active-site iron-sulfide cluster. However, there are no examples of...
Gardado en:
| Publicado en: | J Am Chem Soc |
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| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
American Chemical
Society
2015
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| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4818001/ https://ncbi.nlm.nih.gov/pubmed/26457740 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b06841 |
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