Synthesis, Characterization, and Nitrogenase-Relevant Reactions of an Iron Sulfide Complex with a Bridging Hydride

[Image: see text] The FeMoco of nitrogenase is an iron–sulfur cluster with exceptional bond-reducing abilities. ENDOR studies have suggested that E(4), the state that binds and reduces N(2), contains bridging hydrides as part of the active-site iron-sulfide cluster. However, there are no examples of...

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Bibliografske podrobnosti
izdano v:J Am Chem Soc
Main Authors: Arnet, Nicholas A., Dugan, Thomas R., Menges, Fabian S., Mercado, Brandon Q., Brennessel, William W., Bill, Eckhard, Johnson, Mark A., Holland, Patrick L.
Format: Artigo
Jezik:Inglês
Izdano: American Chemical Society 2015
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC4818001/
https://ncbi.nlm.nih.gov/pubmed/26457740
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b06841
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