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Nitrogenase-Relevant Reactivity of a Synthetic Iron-Sulfur-Carbon Site

Simple synthetic compounds with only S and C donors offer a ligation environment similar to the active site of nitrogenase (FeMoco) and thus demonstrate reasonable mechanisms and geometries for N(2) binding and reduction in nature. We recently reported the first example of N(2) binding at a mononucl...

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Detaylı Bibliyografya
Yayımlandı:J Am Chem Soc
Asıl Yazarlar: Speelman, Amy L., Čorić, Ilija, Van Stappen, Casey, DeBeer, Serena, Mercado, Brandon Q., Holland, Patrick L.
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: 2019
Konular:
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC7251483/
https://ncbi.nlm.nih.gov/pubmed/31403298
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b05353
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