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The Mechanism of N-N Double Bond Cleavage by an Iron(II)-Hydride Complex
The use of hydride species for substrate reductions avoids strong reductants, and may enable nitrogenase to reduce multiple bonds without unreasonably low redox potentials. In this work, we explore the N=N bond cleaving ability of a high-spin iron(II) hydride dimer with concomitant release of H(2)....
Shranjeno v:
| izdano v: | J Am Chem Soc |
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| Main Authors: | , , , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2016
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5499983/ https://ncbi.nlm.nih.gov/pubmed/27598037 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b04654 |
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