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Effects of N(2) Binding Mode on Iron-Based Functionalization of Dinitrogen to Form an Iron(III) Hydrazido Complex

Distinguishing the reactivity differences between N(2) complexes having different binding modes is crucial for the design of effective N(2) functionalizing reactions. Here, we compare the reactions of a K-bridged, dinuclear FeNNFe complex with a monomeric Fe(N(2)) complex where the bimetallic core i...

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Bibliographische Detailangaben
Veröffentlicht in:J Am Chem Soc
Hauptverfasser: McWilliams, Sean F., Bill, Eckhard, Lukat-Rodgers, Gudrun, Rodgers, Kenton R., Mercado, Brandon Q., Holland, Patrick L.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2018
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Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6115203/
https://ncbi.nlm.nih.gov/pubmed/29957940
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b04828
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