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Isolation and Characterization of a High-Spin Mixed-Valent Iron Dinitrogen Complex
We report a rare example of a mixed-valence iron compound with an FeNNFe core, which gives insight into the structural, spectroscopic, and magnetic influences of single-electron reductions and oxidations. In the new compound, the odd electron is localized as judged from Mössbauer spectra at 80 K and...
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| Veröffentlicht in: | Chem Commun (Camb) |
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| Hauptverfasser: | , , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2018
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6258315/ https://ncbi.nlm.nih.gov/pubmed/30403226 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8cc07294a |
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