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Isolation and Characterization of a High-Spin Mixed-Valent Iron Dinitrogen Complex

We report a rare example of a mixed-valence iron compound with an FeNNFe core, which gives insight into the structural, spectroscopic, and magnetic influences of single-electron reductions and oxidations. In the new compound, the odd electron is localized as judged from Mössbauer spectra at 80 K and...

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Bibliografiske detaljer
Udgivet i:Chem Commun (Camb)
Main Authors: McWilliams, Sean F., Bunting, Philip C., Kathiresan, Venkatesan, Mercado, Brandon Q., Hoffman, Brian M., Long, Jeffrey R., Holland, Patrick L.
Format: Artigo
Sprog:Inglês
Udgivet: 2018
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6258315/
https://ncbi.nlm.nih.gov/pubmed/30403226
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8cc07294a
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