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Cooperativity Between Low-Valent Iron and Potassium Promoters in Dinitrogen Fixation
A DFT study was performed to understand the role of cooperativity between iron-β-diketiminate fragments and potassium promoters in N(2) activation. Sequential addition of iron fragments to N(2) reveals that a minimum of three iron centers interact with N(2) in order to break the triple bond. The pot...
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| Autori principali: | , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2012
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3398193/ https://ncbi.nlm.nih.gov/pubmed/22734966 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic300150u |
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