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Diiron bridged-thiolate complexes that bind N(2) at the Fe(II)Fe(II), Fe(II)Fe(I), and Fe(I)Fe(I) redox states
All known nitrogenase cofactors are rich in both sulfur and iron and are presumed capable of binding and reducing N(2). Nonetheless, synthetic examples of transition metal model complexes that bind N(2) and also feature sulfur donor ligands remain scarce. We report herein an unusual series of low va...
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| Udgivet i: | J Am Chem Soc |
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| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2015
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4603983/ https://ncbi.nlm.nih.gov/pubmed/26039253 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b04738 |
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