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Low Temperature N(2) Binding to 2-coordinate L(2)Fe(0) Enables Reductive Trapping of L(2)FeN(2)(−) and NH(3) Generation.
The 2-coordinate (CAAC)(2)Fe complex [CAAC = cyclic (alkyl)(amino)carbene] binds dinitrogen at low temperature (T < −80 °C). The resulting putative 3-coordinate N(2)-complex, (CAAC)(2)Fe(N(2)), was trapped by one electron reduction to its corresponding anion [(CAAC)(2)FeN(2)](−) at low temperatur...
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| Published in: | Angew Chem Int Ed Engl |
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| Main Authors: | , |
| Format: | Artigo |
| Language: | Inglês |
| Published: |
2014
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4314396/ https://ncbi.nlm.nih.gov/pubmed/25394570 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201409454 |
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