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Rh-Catalyzed Intermolecular Reactions of Cyclic α-Diazocarbonyl Compounds with Selectivity Over Tertiary C−H Bond Migration
Intermolecular Rh-catalyzed reactions of cyclic α-diazocarbonyl compounds with chemoselectivity over β-hydride elimination are described. These methods represent the first general intermolecular reactions of Rh-carbenoids that are selective over tertiary β-C−H bond migration. Successful transformati...
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| Main Authors: | , , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2012
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3486930/ https://ncbi.nlm.nih.gov/pubmed/22676258 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja3046712 |
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