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Rh-Catalyzed Intermolecular Reactions of α-Alkyl-α-Diazo Carbonyl Compounds with Selectivity over β-Hydride Migration

Rh-carbenes derived from α-diazocarbonyl compounds have found broad utility across a remarkable range of reactivity, including cyclopropanation, cyclopropenation, C–H insertions, heteroatom–H insertions, and ylide forming reactions. However, in contrast to α-aryl or α-vinyl-α-diazocarbonyl compounds...

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Bibliografiske detaljer
Udgivet i:Acc Chem Res
Main Authors: DeAngelis, Andrew, Panish, Robert, Fox, Joseph M.
Format: Artigo
Sprog:Inglês
Udgivet: 2015
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4898907/
https://ncbi.nlm.nih.gov/pubmed/26689221
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.accounts.5b00425
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