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Rh-Catalyzed Intermolecular Reactions of Cyclic α-Diazocarbonyl Compounds with Selectivity Over Tertiary C−H Bond Migration

Intermolecular Rh-catalyzed reactions of cyclic α-diazocarbonyl compounds with chemoselectivity over β-hydride elimination are described. These methods represent the first general intermolecular reactions of Rh-carbenoids that are selective over tertiary β-C−H bond migration. Successful transformati...

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Detalhes bibliográficos
Main Authors: DeAngelis, Andrew, Dmitrenko, Olga, Fox, Joseph M.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3486930/
https://ncbi.nlm.nih.gov/pubmed/22676258
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja3046712
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