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Rhodium‐Catalyzed Geminal Oxyfluorination and Oxytrifluoro‐Methylation of Diazocarbonyl Compounds

A new reaction for the rhodium‐catalyzed geminal‐difunctionalization‐based fluorination is presented. The substrates are aromatic and aliphatic diazocarbonyl compounds. As the fluorine source a stable and easily accessible benziodoxole reagent was used. A variety of alcohol, phenol, and carboxylic a...

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Foilsithe in:Angew Chem Int Ed Engl
Main Authors: Yuan, Weiming, Eriksson, Lars, Szabó, Kálmán J.
Formáid: Artigo
Teanga:Inglês
Foilsithe: John Wiley and Sons Inc. 2016
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC5089581/
https://ncbi.nlm.nih.gov/pubmed/27219856
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201602137
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