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Rhodium(II)-Catalyzed Enantioselective C–H Functionalization of Indoles

A catalytic, enantioselective method for the C–H functionalization of indoles by diazo compounds has been achieved. With catalytic amounts of Rh(2)(S-NTTL)(4), the putative Rh-carbene intermediates from α-alkyl-α-diazoesters react with indoles at C(3) to provide α-alkyl-α-indolylacetates in high yie...

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Main Authors: DeAngelis, Andrew, Shurtleff, Valerie W., Dmitrenko, Olga, Fox, Joseph M.
Formáid: Artigo
Teanga:Inglês
Foilsithe: 2011
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC3144986/
https://ncbi.nlm.nih.gov/pubmed/21265565
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja1093309
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