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Rhodium(II)-Catalyzed Enantioselective C–H Functionalization of Indoles
A catalytic, enantioselective method for the C–H functionalization of indoles by diazo compounds has been achieved. With catalytic amounts of Rh(2)(S-NTTL)(4), the putative Rh-carbene intermediates from α-alkyl-α-diazoesters react with indoles at C(3) to provide α-alkyl-α-indolylacetates in high yie...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3144986/ https://ncbi.nlm.nih.gov/pubmed/21265565 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja1093309 |
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