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Synthesis of Alkaloid (−)-205B via Stereoselective Reductive Cross-Coupling and Intramolecular [3+2] Annulation

An asymmetric synthesis of alkaloid (−)-205B, a tricyclic member of the architecturally diverse family of natural products isolated from the skin of neotropical poison frogs, is described that proceeds through two recently developed stereoselective synthetic methods: (1) Ti-mediated allylic alcohol–...

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Detalhes bibliográficos
Main Authors: Yang, Dexi, Micalizio, Glenn C.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3470905/
https://ncbi.nlm.nih.gov/pubmed/22957796
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja306362m
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