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An Alkoxide-Directed Alkyne–Allene Cross-Coupling for Stereoselective Synthesis of 1,4-Dienes

A titanium alkoxide-mediated convergent coupling between internal alkynes and allenes is described for the regio- and stereocontrolled synthesis of substituted acyclic 1,4-dienes.

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Detalles Bibliográficos
Publicado en:Chem Commun (Camb)
Main Authors: Shimp, Heidi L., Micalizio, Glenn C.
Formato: Artigo
Idioma:Inglês
Publicado: 2007
Assuntos:
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC4319186/
https://ncbi.nlm.nih.gov/pubmed/17971979
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/b708256h
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