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Synthesis of the Cortistatin Pentacyclic Core by Alkoxide-Directed Metallacycle-Mediated Annulative Cross-Coupling

The pentacyclic core skeleton of the cortistatins has been prepared in a stereoselective fashion by strategic use of an alkoxide-directed metallacycle-mediated annulative cross-coupling. This metal-centered tandem reaction delivers a polyunsaturated hydrindane and establishes the C13 stereodefined q...

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Bibliografische gegevens
Gepubliceerd in:Org Lett
Hoofdauteurs: Aquino, Claudio, Greszler, Stephen N., Micalizio, Glenn C.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2016
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Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4892975/
https://ncbi.nlm.nih.gov/pubmed/27193994
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.6b01048
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