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Synthesis of Angularly Substituted trans-Fused Decalins by a Metallacycle-Mediated Annulative Cross-Coupling Cascade
A convergent coupling reaction is described that enables the stereoselective construction of angularly substituted trans-fused decalins from acyclic precursors. The process builds on our alkoxide-directed titanium-mediated alkyne–alkyne coupling and employs a 1,7-enyne coupling partner. Overall, the...
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| Izdano u: | Angew Chem Int Ed Engl |
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| Glavni autori: | , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2016
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5056368/ https://ncbi.nlm.nih.gov/pubmed/27634059 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201606962 |
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