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Acceleration of metallacycle-mediated alkyne–alkyne cross-coupling with TMSCl
Investigation of titanium-centered metallacycle-mediated cross-coupling between unsymmetrical internal alkynes has led to the discovery that TMSCl significantly accelerates the C–C bond forming event. We report a collection of results that compare the efficiency of this reaction employing Ti(Oi-Pr)(...
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| Published in: | Tetrahedron Lett |
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| Main Authors: | , , |
| Format: | Artigo |
| Language: | Inglês |
| Published: |
2016
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5046837/ https://ncbi.nlm.nih.gov/pubmed/27713588 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2016.07.045 |
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