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Cyclopropenes in Metallacycle-Mediated Cross-Coupling with Alkynes: Convergent synthesis of highly substituted vinylcyclopropanes

Stereodivergent metallacycle-mediated cross-coupling reactions are described for the synthesis of densely functionalized vinylcyclopropanes from the union of alkynes with cyclopropenes. Strategies explored include hydroxyl-directed and non-directed processes, with the latter of these delivering viny...

詳細記述

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書誌詳細
出版年:Org Lett
主要な著者: O’Rourke, Natasha F., Micalizio, Glenn C.
フォーマット: Artigo
言語:Inglês
出版事項: 2016
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC4882924/
https://ncbi.nlm.nih.gov/pubmed/26987882
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.6b00072
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