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Cyclopropenes in Metallacycle-Mediated Cross-Coupling with Alkynes: Convergent synthesis of highly substituted vinylcyclopropanes

Stereodivergent metallacycle-mediated cross-coupling reactions are described for the synthesis of densely functionalized vinylcyclopropanes from the union of alkynes with cyclopropenes. Strategies explored include hydroxyl-directed and non-directed processes, with the latter of these delivering viny...

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Detalhes bibliográficos
Publicado no:Org Lett
Main Authors: O’Rourke, Natasha F., Micalizio, Glenn C.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4882924/
https://ncbi.nlm.nih.gov/pubmed/26987882
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.6b00072
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