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Total Synthesis of Lehualide B by Allylic Alcohol–Alkyne Reductive Cross-Coupling

[Image: see text] The total synthesis of anticancer marine natural product lehualide B is described. Overall, the synthesis proceeds in just eight steps from a simple γ-pyrone, does not require the use of protecting groups, and delivers each nonconjugated trisubstituted alkene with high levels of st...

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Detalhes bibliográficos
Main Authors: Jeso, Valer, Micalizio, Glenn C.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2923668/
https://ncbi.nlm.nih.gov/pubmed/20681603
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja104782u
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