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Complex Allylation by the Direct Cross-Coupling of Imines with Unactivated Allylic Alcohols

[Image: see text] We report a reaction for the convergent coupling of allylic alcohols with imines that delivers stereodefined homoallylic amines. The process proceeds with net allylic transposition, without the intermediacy of allylic organometallic reagents, and forges two stereodefined centers an...

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Detalhes bibliográficos
Main Authors: Takahashi, Masayuki, McLaughlin, Martin, Micalizio, Glenn C.
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3028933/
https://ncbi.nlm.nih.gov/pubmed/19360820
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.200900236
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