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Concerning the Potential Reversibility of Carbometalation in Alkoxide-directed Ti(Oi-Pr)(4)-mediated Reductive Cross-Coupling of Homoallylic Alcohols with Aromatic Imines

In an attempt to understand the nature of selectivity in Ti-mediated reductive cross-coupling between homoallylic alcohols and imines, we investigated whether thermodynamic equilibration of the presumed organometallic intermediate plays a role in selectivity. No evidence could be found for olefin ex...

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Detalhes bibliográficos
Main Authors: Takahashi, Masayuki, Micalizio, Glenn C.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3023109/
https://ncbi.nlm.nih.gov/pubmed/20379585
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/b927430h
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