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Concerning the Potential Reversibility of Carbometalation in Alkoxide-directed Ti(Oi-Pr)(4)-mediated Reductive Cross-Coupling of Homoallylic Alcohols with Aromatic Imines
In an attempt to understand the nature of selectivity in Ti-mediated reductive cross-coupling between homoallylic alcohols and imines, we investigated whether thermodynamic equilibration of the presumed organometallic intermediate plays a role in selectivity. No evidence could be found for olefin ex...
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| Main Authors: | , |
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| Formáid: | Artigo |
| Teanga: | Inglês |
| Foilsithe: |
2010
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| Ábhair: | |
| Rochtain Ar Líne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3023109/ https://ncbi.nlm.nih.gov/pubmed/20379585 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/b927430h |
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