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Polyketide Assembly by Alkene–Alkyne Reductive Cross-Coupling: Spiroketals Through the Union of Homoallylic Alcohols
[Image: see text] A reaction sequence composed of regioselective formal hydroalkynylation, reductive ene-yne cross-coupling and oxidative cyclization has been developed to prepare stereochemically dense spiroketals. Overall, the chemistry defines a three-component coupling process for the union of t...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2010
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2892691/ https://ncbi.nlm.nih.gov/pubmed/20476790 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja102888f |
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