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Stereochemistry of electrophilic attack at 34e(−) dimetallic complexes: the case of diiron dithiolato carbonyls + MeS(+)
Experimental and computational experiments show that the electrophile MeS(+) attacks a single Fe center in Fe(2)(propanedithiolate)(CO)(4)(PMe(3))(2) followed by isomerization of this terminal thiolato complex to the corresponding μ-SMe derivative.
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3465568/ https://ncbi.nlm.nih.gov/pubmed/21776614 |
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