Stereochemistry of electrophilic attack at 34e(−) dimetallic complexes: the case of diiron dithiolato carbonyls + MeS(+)

Experimental and computational experiments show that the electrophile MeS(+) attacks a single Fe center in Fe(2)(propanedithiolate)(CO)(4)(PMe(3))(2) followed by isomerization of this terminal thiolato complex to the corresponding μ-SMe derivative.

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Bibliografiske detaljer
Main Authors: Olsen, Matthew T., Gray, Danielle L., Rauchfuss, Thomas B., De Gioia, Luca, Zampella, Giuseppe
Format: Artigo
Sprog:Inglês
Udgivet: 2011
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Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3465568/
https://ncbi.nlm.nih.gov/pubmed/21776614
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