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Reaction of Aryl Diazonium Salts and Diiron(I) Dithiolato Carbonyls: Evidence for Radical Intermediates
Treatment of Fe(2)(pdt)(CO)(4)(dppv) (1) with aryldiazonium salts affords the 34e(−) adducts [Fe(2)(pdt)(μ-N(2)Ar)(CO)(4)(dppv)](+) (pdt(2−) = 1,3-propanedithiolate, dppv = cis-C(2)H(2)(PPh(2))(2)). Under some conditions, the same reaction gave substantial amounts of [1](+), the product of electron-...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3434965/ https://ncbi.nlm.nih.gov/pubmed/22962513 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om300107s |
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